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981.
Fanhao Zeng Xiang Xiong Baiyun Huang 《Applied Physics A: Materials Science & Processing》2010,99(2):459-463
High-quality Co(Cr)(50–66 nm)/Ti(Cr)(25–30 nm)/ZnO(165–225 nm) films were grown on Si substrates by the pulsed-laser deposition
technique at 450–500°C. The microstructure of the films and their magnetic properties were investigated by X-ray diffraction,
transmission electron microscopy and a vibrating sample magnetometer. It was found that the Co(Cr)/Ti(Cr)/ZnO thin films had
a highly preferential c-axis direction normal to the surface of the substrate, and the ZnO sublayer had columnar structures in the growth direction.
The interface of the multi-layer films is smooth without interface reaction. The as-produced films had in-plane easy magnetization.
It indicates that the enhancements of the magnetic properties of the films are mainly ascribed to the grain structure and
multi-domain state of the Co-alloy layer, which can be controlled by the ZnO sublayer. 相似文献
982.
983.
The nonextensive thermodynamic relations are expressed under the assumption of temperature duality, endowing the “physical temperature” and the “Lagrange temperature” in different physical senses. Based on this assumption, two sets of parallel Legendre transform structures are given. One is called “physical” set, and the other is called “Lagrange” set. In these two formalisms, the thermodynamic quantities and the thermodynamic relations are both liked through the Tsallis factor. Application of the two sets of the thermodynamic relations to the self-gravitating system shows that the heat capacity defined in the classical thermodynamics has no relevance to the stability of the system. Instead, the newly defined heat capacity can determine the stability of the system. 相似文献
984.
A new zinc coordination polymer, [Zn(L)(bpp)·H2O]n, was synthesized using 5-dimethylamino-isophthalic acid (H2L) and 1,3-bis(4-pyridyl)propane (bpp) as organic linkers. In the complex, adjacent Zn2+ ions are linked by L2? anions to form a one-dimensional (1D) [ZnL]n chain. Then bpp ligands expand the 1D chains into a corrugated two-dimensional (2D) layer network by linking neighboring Zn2+ ions. These adjacent layers are further stacked together by direct C?H···π supramolecular interactions, generating a three-dimensional (3D) supramolecular structure. From the viewpoint of topology, the 2D network can be rationalized to a uninodal four-connected non-interpenetrated sql/Shubnikov tetragonal plane net with {44.62} topology. Moreover, the solid state properties such as thermogravimetric analysis and luminescence were also investigated. 相似文献
985.
Lei Sun Tian Du Cheng Wang Prof. Dongling Geng Dr. Lin Li Prof. Yang Han Prof. Yunfeng Deng 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(69):17437-17443
Low-bandgap organic semiconductors have attracted much attention for their multiple applications in optoelectronics. However, the realization of narrow bandgap is challenging particularly for small molecules. Herein, we have synthesized four quinoidal compounds, i. e., QSN3 , QSN4 , QSN5 and QSN6 , with electron rich S,N-heteroacene as the quinoidal core and indandione as the end-groups. The optical bandgap of the quinoidal compounds is systematically decreased with the extension of quinoidal skeleton, while maintaining stable closed-shell ground state. QSN6 absorbs an intense absorption in the first and second near-infrared region in the solid state, and has extremely low optical bandgap of 0.74 eV. Cyclic voltammetry analyses reveal that the lowest unoccupied molecular orbital (LUMO) energy levels of the four quinoidal compounds all lie below −4.1 eV, resulting in good electron-transporting characteristics in organic thin-film transistors. These results demonstrated that the combination of π-extended quinoidal core and end-groups in quinoidal compounds is an effective strategy for the synthesis of low-bandgap small molecules with good stability. 相似文献
986.
987.
Bin Du Adam Langlois Daniel Fortin Christine Stern Pierre D. Harvey 《Journal of Cluster Science》2012,23(3):737-751
The title cluster is luminescent at 77?K and exhibits an unsaturated site for binding anions when the counter ion is PF6 ?. A series of five non-luminescent metalloporphyrins exhibiting carboxylate anchoring groups were synthesized and characterized. These are the sodium salts of the 5-carboxyphenyl-tri-10,15,20-tolyl-, trans-di-5,10-carboxyphenyl-di-15,20-tolyl-, and tetra-5,10,15,20-carboxyphenyl(metallo)porphyrin (metallo?=?chloroiron(III), nickel(II)) anions. Evidence for supramolecular assemblies between the carboxylates and the cluster is provided by 31P NMR and UV?Cvis spectroscopy. The binding constant, K1n, extracted from the UV?Cvis data via Benesi-Hildebrand, Scott and Scatchard plots are approximately 21,000?±?5,000?M?1 for the nickel(II) species, in agreement with the previously reported zinc(II) ones (K11?=?20,000?±?2,000?M?1), but those for the chloroiron(III) are measured to be lower (12,500?±?3,500?M?1). This association is accompanied by a complete quenching of the luminescence of the cluster which can only be due to an efficient energy transfer to the d?Cd states of the chloroiron(III) and nickel(II) species but an electron transfer from the nickel(II)-containing chromophore to the cluster is also possible. This work demonstrates the profound effect that supramolecular interactions may have on the photophysical properties despite the long donor?Cacceptor separation. 相似文献
988.
989.
In this paper, we discuss the globalization of some kind of modified Levenberg-Marquardt methods for nonsmooth equations and
their applications to nonlinear complementarity problems. In these modified Levenberg-Marquardt methods, only an approximate
solution of a linear system at each iteration is required. Under some mild assumptions, the global convergence is shown. Finally,
numerical results show that the present methods are promising. 相似文献
990.